Extensive use of social networking sites by students and teachers makes educators and researchers to think whether they can be incorporated in instructional process to facilitate students' learning. This survey-based study records and examines Pakistani pre-service teachers' and teacher-educators' current uses of Facebook, and their attitudes toward using Facebook for collaborative learning, and to see if there is a significant relationship between participants' intensity of Facebook use and their attitude toward instructional use of Facebook. Results of the study indicated that pre-service teachers' and teacher-educators' motives for their current Facebook use are mainly limited for social purposes. Pre-service teachers' use of Facebook is more intensified than the use of Facebook by teacher-educators. Further, pre-service teachers showed more positive attitudes toward using Facebook for collaborative learning than the attitudes of their faculty. Findings also indicated a positive relationship between participants' Facebook intensity and their attitudes toward its use for collaborative learning.