Single-crystal X-ray structures, melting points, and students' specific rotation results on carvone semicarbazone derivatives are presented with experimental details. Critical parameters are identified to ensure the success of the experiment. Procedures developed here were tested in a laboratory course, consisting of approximately 70 students over…

An integrated laboratory experiment applying concepts and techniques from organic chemistry, inorganic chemistry, and instrumental analysis is presented for use in the undergraduate curriculum. This experiment highlights the synthesis, characterization, and use of tris(2-pyridylmethyl)amine (TPMA) to make complexes with different metal salts. It…

Computational approaches toward simulating chemical systems and evaluating experimental data has gathered great momentum in recent years. The onset of more powerful computers and advanced software has been instrumental to this end. This manuscript presents a hands-on activity which trains students in basic coding skills within the Matlab…

A laboratory experiment that involves the synthesis, characterization, and application exploration of a metal-organic framework (MOF) has been developed for first-year undergraduates in the Faculty of Engineering at National University of Singapore. The desired MOF material was prepared from commercially available reagents in a facile…

This manuscript describes a laboratory experiment that provides students with an opportunity to create conductive silver nanogrids using polymeric templates. A microcontact-printed polyvinylpyrrolidone grid directs the citrate-induced reduction of silver ions for the fabrication of silver nanogrids on glass substrates. In addition to…

In the field of "hydrogen energy", sodium borohydride (NaBH[subscript 4]) is a potential hydrogen carrier able to release H[subscript 2] by hydrolysis in the presence of a metal catalyst. Our laboratory experiment focuses on this. It is intended for thirdyear undergraduate students in order to have hands-on laboratory experience through…

An integrated and research-focused laboratory experiment is developed to introduce the "antenna effect" occurring in luminescent lanthanide complexes to students. Students synthesized a lanthanide metal-organic framework (Ln-MOF) with the formula of [Eu(BTPCA)(H O)]·2DMF·nH[Subscript 2]O (Eu-BTPCA, H[subscript 3]BTPCA =…

Biocompatible and biodegradable block copolymers composed of poly(ethylene glycol) (PEG) and aliphatic polyester are a class of promising biomaterials. Herein, a teaching experiment was designed to furnish undergraduates with a reliable method to synthesize an amphiphilic poly([epsilon]-caprolactone)-PEG-poly([epsilon]-caprolactone) (PCL-PEG-PCL)…

Novel carbon nanomaterials such as reduced graphene oxide (rGO) and graphene oxide (GO) can be easily incorporated into the undergraduate curriculum to discuss basic chemistry and nanotechnology concepts. This paper describes a laboratory experiment designed to study the differences between GO and rGO regarding their physicochemical properties…

This paper summarizes a project seminar in analytical chemistry that includes a method comparison approach and collaborative learning. In this project seminar, 12 students worked in four groups, each of which focused on one method for quantitative element analysis, including flame atomic absorption spectroscopy, inductively coupled plasma mass…

Perovskite solar cells have garnered exponential research interest due to their facile fabrication, solution processability, and low cost. However, there have been limited efforts to integrate this class of materials into the undergraduate laboratory curriculum. Therefore, we designed an integrated laboratory experiment in our upper-division…

Zeolite Y has an iconic crystal structure, but more importantly, the hydrogen modification zeolite H-Y is the classic example of a solid acid which is used extensively as a catalyst in the oil industry. This metastable compound cannot be synthesized directly, which creates an opportunity to discuss various preparative strategies with the students,…

A simple and straightforward synthesis of an ultrastable porous metal-organic framework (MOF) based on copper(II) and a mixed N donor ligand system is described as a laboratory experiment for chemistry undergraduate students. These experiments and the resulting analysis are designed to teach students basic research tools and procedures while…

Graphene has opened up new opportunities for scientific and technological innovations because of its astonishing electrical, mechanical, chemical, and thermal properties. For instance, graphene-based nanocomposites have found extensive applications in Li-ion batteries (LIBs) as scientists and engineers seek to achieve superior electrochemical…

A new solvent-free microwave experiment to synthesize the ionic liquid 1-hexadecyl-3-methylimidazolium bromide (HDMIm-Br) in high yield is presented. The structure is confirmed by IR and [superscript 1]H NMR spectra. HDMIm-Br is then used to prepare an organic-inorganic mesoporous material MCM-41. The microscopic arrangements of mesoporous…