This study evaluated the dimensionality of the construct of social problem solving and examined the relationships between social problem solving and empathy, emotional well-being and family well-being in a sample of secondary school students in Hong Kong (N = 1462). The participants completed measures of social problem solving (the 25-item short form of the Chinese version of the Social Problem-Solving Inventory: C-SPSI-R), empathy (the Chinese Interpersonal Reactivity Scale), emotional well-being (the Chinese Vengeance Scale) and family well-being (the Chinese Family Assessment Instrument and the Conflict Behaviour Questionnaire). Regarding the dimensionality of the C-SPSI, confirmatory factor analysis showed that the scale has a stable five-factor structure (RMSEA = 0.05) and that the related subscales were reliable (with ranging from 0.65 to 0.81). Participants with higher levels of social problem solving had higher levels of empathy and lower personal distress in applying empathy, which suggested that these personal competencies were inter-related. Higher levels of social problem solving were also related to better emotional well-being (less tendency to take revenge) and better family quality of life (better family functioning and fewer parent-adolescent conflicts).