A eutectic system is a mixture of two or more substances, displaying a melting temperature lower than its standalone components. The eutectic composition displays the lowest melting temperature of all mixtures. Typically, a eutectic system is used as an example of binary phase diagrams to demonstrate to undergraduate students. Herein, the liquidus…

A new method to determine a ternary phase diagram of benzene-acetic acid-water system is provided to upper-division undergraduate students. The partially miscible liquid phase region can be accurately constructed using isothermal titration microcalorimetry (ITC). Compared with the traditional visual method, ITC can provide precise data and more…

A remote experiment was developed and carried out to create a phenol/water phase diagram using a low-cost automated data collection system and an online video broadcast. Both the data and video from the experiment were transmitted in real-time. The remote lab experiment was evaluated using qualitative and quantitative questionnaires filled out by…

In this work, we venture to show how careful use of a program for quantum chemical calculations (such as VASP) may enrich teaching in solid-state chemistry and how principles of thermodynamics contribute to a validation of phase diagrams and reaction pathways using the quasiternary system Li[subscript 2]O-Al[subscript 2]O[subscript…

Through the experiments described in this article, students become acquainted with the principles behind ternary liquid-liquid systems and/or Aqueous Two-Phase Systems (ATPS), and their characterization by the determination of the binodal curve, tie-lines, tie-line lengths and critical point, as well as in applying the non-random two-liquid model…

A good understanding of ternary phase diagrams is required to advance and/or to reproduce experimental research in solid-state and materials chemistry. The aim of this paper is to describe the solutions to problems that appear when studying or determining ternary phase diagrams. A brief description of the principal features shown in phase diagrams…

The determination of the solid-liquid phase diagram of a binary system is always used as an experiment in the undergraduate physical chemistry laboratory courses. However, most phase diagrams investigated in the lab are simple eutectic ones, despite the fact that complex binary solid-liquid phase diagrams are more common. In this article, the…

Despite the interesting applications that the PDF-3D offers in teaching, especially for subjects related to spatial comprehension difficulties, such a didactic tool is not well known in the education sector. Thus, a proposal of using PDF-3D in engineering studies is presented in this paper, specifically, in the field of teaching ternary phase…

Space-related activities remain a fertile environment for classroom applications of chemistry through both traditional lecture styles and through collaborative learning projects. With the resurgence of lunar exploration and the expansion of the commercial space sector, serious scholarship, planning, and resources have been focused on extracting…

The principles of process-oriented guided inquiry learning (POGIL) are applied to a binary solid-liquid mixtures experiment. Over the course of two learning cycles, students predict, measure, and model the phase diagram of a mixture of fatty acids. The enthalpy of fusion of each fatty acid is determined from the results. This guided inquiry…

The lever rule applies to any two-component system existing in a state of two-phase equilibrium. Here, several classroom demonstrations are described to help students understand liquid--liquid coexistence and the lever rule using a set of isobutyric acid + water + dye samples ranging in composition from water + dye to isobutyric acid + dye. The…

A safe and inexpensive laboratory for a first-year general chemistry course has been developed which allows students to explore important properties of carbon dioxide, particularly its behavior as a greenhouse gas. Students witness and measure air displacement to compare calculated gas densities and pressures inside a CO[subscript 2]-filled…

An experiment focusing on the creation of phase diagrams involving nonconvalent derivatives of hydroquinone and bis[N,N-diethyl]terephthalamide (HQ-DETPA) is presented. A phase diagram was assembled by taking samples of different compositions (i.e., 40% hydroquinone and 60% bis[N,N-diethyl]terephthalamide, 70%/30%, etc.) and determining the…

In place of a traditional Advanced Placement Chemistry class at the high school where I teach, I have recently developed and implemented a year-long, interdisciplinary curriculum that presents typical inorganic chemistry topics in the context of their relevant applications in archeology, art history, studio art, and the investigation,…

Characterization of the vapor pressure of a volatile liquid or azeotropic mixture, and its fluid phase diagram, can be achieved with an isoteniscope and an industrial grade digital pressure sensor using the experimental method reported in this study. We describe vapor-pressure measurements of acetone and n-hexane and their azeotrope, and how the…