Raman spectroscopy is a powerful experimental technique, yet it is often missing from the undergraduate physical chemistry laboratory curriculum. Tetrachloromethane (CCl[subscript 4]) is the ideal molecule for an introductory vibrational spectroscopy experiment and the symmetric stretch vibration contains fine structure due to isotopic variations of the molecule according to C[superscript 35]Cl[subscript x][superscript 37]Cl[subscript 4-x]. We report simple theoretical predictions of the fine structure, calculation of Raman differential scattering cross sections, and discussion of the inherent asymmetry in the v[subscript 1] mode resulting from the different isotopes of chlorine. All calculations and discussion are appropriate for an undergraduate physical chemistry laboratory as either an independent dry lab or a supplement to a pre-existing vibrational spectroscopy lab.