This paper offers a critical examination of the nature of inequalities in relation to education and the pursuit of social justice. It argues that assessment of educational resources and measures such as school enrolment and educational achievement are limited in what they tell us about the injustices learners may experience. It is proposed that, drawing on Amartya Sen's capability approach, we benefit from extending our evaluative space beyond learners' achievements to encompass their freedoms to achieve. It is argued that attention should be paid to the relative value individuals place on these various freedoms. Furthermore, in order to deepen insights into the multiple factors influencing the development of learner values, and the unequal possibilities for realising their aspired valued achievements, the discussion also draws on key sociological concepts from Pierre Bourdieu. The theoretical synthesis leads to the introduction of the Sen-Bourdieu Analytical Framework, a conceptual model that illustrates the socially dynamic processes within which learners and formal educational systems are situated. The principal aims are to offer an alternative development paradigm and an expanded evaluative framework to inform local, national and international educational policy and practice.