This study investigated the introduction of the second law of thermodynamics using the Legitimation Code Theory (LCT) (semantic waves) among first year chemistry students. The aim of the study was to investigate the extent LTC (semantic waves) reduce the entropy concept's complexity and abstractness when introducing the second law of…

Historically, classical thermodynamics was developed during attempts to improve the efficiency of steam engines. Those investigations led to the well-known zeroth, first, and second laws of thermodynamics. Although these laws are presented independently, linkages between the zeroth and second laws have been pointed out in the physics teaching…

This study aimed to determine the relationships that prospective science teachers have established between thermodynamics and environmental problems. The study was conducted with the case study method. The sample consisted of 74 senior prospective science teachers selected by purposive sampling and studied in Science Teaching Department in the…

The first law of thermodynamics involves several types of energies and many studies have shown that students lack awareness of them. They have difficulties in applying the law to different thermodynamic processes. These observations were confirmed in our pilot studies, carried out with students from undergraduate colleges across the whole of…

The change in enthalpy of a chemical reaction conducted at constant pressure is equal to the heat of the reaction plus the nonexpansion work of the reaction, ?H = qP + w[subscript additional]. After deriving that relationship, most general and physical chemistry textbooks set w[subscript additional] = 0 to arrive at the claim that ?H = qP, and…

Breathing is something we all do, usually without thinking about it. But when viewed through the lens of physics, respiration becomes an example of elementary thermodynamics. As shown here, the lungs can be modeled as a two-stroke heat engine. Breathing thereby provides a novel physics application for life science students, demonstrating the…

What if energy flowed from cold to hot regions? How would thermodynamics be different? We examine such an imagined cold-to-hot world, abbreviated here as a C2H world, and show that the unfamiliar direction of energy flow implies that two thermally interacting objects at different temperatures will not equilibrate. We find that there is no…

A widespread call has been made to develop and support more integrated approaches to STEM education. The first law of thermodynamics serves as a guiding principle for the crosscutting concept of energy and matter. A qualitative interview study was undertaken to support integrated approaches to STEM education by exploring how chemistry, physics,…

Pregraduate students often have low success expectations toward their thermodynamics courses, which are often considered too abstract and remarkably difficult to understand. For this reason, they may not even try to reach any level of comprehension while settling for reproducing mathematical calculations and memorizing definitions to pass the…

The first law of thermodynamics does not forbid heat engines with 100% thermodynamic efficiency; it is the second law of thermodynamics which states that heat engines cannot obtain 100% efficiency. Can the first law ever show this second law result? Yes. We show that the first law alone can show that some heat engines cannot achieve efficiencies…

The second law of thermodynamics has various formulations. There is the "Clausius formulation," which can be stated in a very intuitive way: "No process is possible whose sole result is the transfer of heat from a cooler to a hotter body." There is also the "Kelvin-Plank principle," which states that "no cyclic…

Teaching and learning introductory thermodynamics has drawn considerable research attention over the last two decades, especially in several disciplines of higher education. Under particular investigation is the First Law of Thermodynamics (FLT), which offers an expression of energy conservation in thermodynamic systems, as the evidence shows that…

Obesity is the costliest preventable health problem in the United States. Understanding and applying the first law of thermodynamics will help students prevent and treat this all-too-common problem.

Fundamentals of Macroscopic Chemical Analysis is a newly developed foundation-level course that integrates concepts from traditional physical and analytical chemistry courses. The course was designed to serve majors in chemistry, biochemistry, and biology as well as pre-health professional students. The main goal of this course is to develop the…

An alternative method of presenting the second law of thermodynamics in introductory courses is presented. The emphasis is on statistical approaches as developed by Atkins. This has the benefit of stressing the statistical nature of the law.