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Wagner, Carl E.; Marshall, Pamela A. – Journal of Chemical Education, 2010
This laboratory experiment was developed to provide a safe, economical, and effective way to instruct undergraduate organic chemistry students about the unimolecular nucleophilic substitution (S[subscript N]1) reaction. Students treat 2,5-dimethyl-2,5-hexanediol with excess concentrated hydrochloric acid to synthesize…
Descriptors: Organic Chemistry, Laboratory Experiments, Science Instruction, College Science
Anderson, Bruce D.; Gordon, Christopher M. – Journal of Chemical Education, 2008
In this experiment, linear polyynes are synthesized and then the predictions of a one-dimensional, particle in a box are used to calculate the quantum mechanical box length for the polyynes. A solution of graphite in ethanol is irradiated with a Nd:YAG laser (532 nm) and the resulting solution is filtered and analyzed. Data from gas…
Descriptors: Quantum Mechanics, Physics, Chemistry, Lasers