ERIC Number: EJ1256611
Record Type: Journal
Publication Date: 2020-Jun
Pages: 6
Abstractor: As Provided
ISBN: N/A
ISSN: ISSN-0021-9584
EISSN: N/A
A Closer Examination of the Mechanism of the Hydrogen Peroxide Iodine-Clock Reaction with Respect to the Role of Hypoiodite Species
Journal of Chemical Education, v97 n6 p1688-1693 Jun 2020
One step of the published mechanism of the hydrogen peroxide iodine-clock reaction is called into question by the result of an experimental attempt (predicated on that mechanism) to integrate that reaction into the elephant's toothpaste demonstration to reveal and control its iodine side product. Under conditions that were a hybrid of those demonstrations (starch and thiosulfate added to the elephant's toothpaste demonstration), there was a pronounced induction period preceding the appearance of both iodine and oxygen. This induction period for "both" of these products indicated that the reductant reacted not with iodine but with the transient intermediate, hypoiodous acid (or hypoiodite), common to both iodine and oxygen generation. Additional experiments based on the reaction of thiosulfate with 8 times more moles of hypoiodite than moles of iodine supported this conclusion.
Descriptors: Chemistry, Science Instruction, Science Laboratories, Science Experiments, Misconceptions
Division of Chemical Education, Inc. and ACS Publications Division of the American Chemical Society. 1155 Sixteenth Street NW, Washington, DC 20036. Tel: 800-227-5558; Tel: 202-872-4600; e-mail: eic@jce.acs.org; Web site: http://pubs.acs.org/jchemeduc
Publication Type: Journal Articles; Reports - Evaluative
Education Level: N/A
Audience: N/A
Language: English
Sponsor: N/A
Authoring Institution: N/A
Grant or Contract Numbers: N/A