ERIC Number: EJ1231285
Record Type: Journal
Publication Date: 2019-Oct
Pages: 8
Abstractor: As Provided
ISBN: N/A
ISSN: ISSN-0021-9584
EISSN: N/A
Demystifying Mathematical Modeling of Electrochemical Systems
Journal of Chemical Education, v96 n10 p2217-2224 Oct 2019
One of the unique advantages of electrochemistry is that the relationship between thermodynamics and kinetics is quantitative, which is the basis of voltammetry. Mathematical models of electrochemical systems take advantage of this relationship to predict the effect of changing a system property (e.g., concentration, scan rate, or rate constant) with high accuracy. This insight enhances understanding of the link between experimental settings and their resulting effects and further allows optimal values to be determined before the experiment begins. This work introduces the electrochemical theory and process of building one of these models for an example system of ferricyanide undergoing reduction during a linear sweep voltammogram, a common experiment in undergraduate laboratories. A MATLAB code for finite difference implementation of this model is provided, as well as a list of suggested exercises for modifying or extending this code, which could be used a problem set in undergraduate or graduate course work.
Descriptors: Chemistry, Mathematical Models, Thermodynamics, Kinetics, College Science, Computer Uses in Education, Science Instruction, Theories, Science Activities
Division of Chemical Education, Inc. and ACS Publications Division of the American Chemical Society. 1155 Sixteenth Street NW, Washington, DC 20036. Tel: 800-227-5558; Tel: 202-872-4600; e-mail: eic@jce.acs.org; Web site: http://pubs.acs.org/jchemeduc
Publication Type: Journal Articles; Reports - Descriptive
Education Level: Higher Education; Postsecondary Education
Audience: N/A
Language: English
Sponsor: N/A
Authoring Institution: N/A
Grant or Contract Numbers: N/A