The aim of this study was to analyze the correlation among teachers' perceived acceptance of technological innovation, organisations' innovation climate, and innovative teaching using information and communication technology (ICT) in Taiwan. The participants (N = 482) responded to a questionnaire using a five-point Likert scale for each factor, and their responses were analyzed using structural equation modeling (SEM). This research found that an organisation's innovation climate is significantly and positively related with innovative teaching using ICT, and that the acceptance of technological innovation is significantly and positively related with innovative teaching using ICT, as supported by the organisation's innovation climate. The influence pattern and empirical data of the acceptance of technological innovation and the organisation's innovation climate on innovative teaching with ICT exhibited a good fit. The implications of such findings were discussed.