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ERIC Number: EJ1195698
Record Type: Journal
Publication Date: 2018-Sep
Pages: 9
Abstractor: As Provided
ISBN: N/A
ISSN: ISSN-0021-9584
EISSN: N/A
Orbital Configuration: Terms, States, and Configuration State Functions
Brom, Joseph M.
Journal of Chemical Education, v95 n9 p1592-1600 Sep 2018
Molecular orbital configurations give rise to electronic terms comprising corresponding electronic states. Electronic terms possess symmetry classifications, which are denoted by a term symbol, based on the symmetry properties of the electronic wave functions associated with the states. Using the methylene radical, and both planar and twisted ethylene molecules as examples, the symmetry classifications of the wave functions connected to orbital configurations are determined. The wave functions associated with the open-shell ···(2e)[superscript 2] ground configuration of twisted, D[subscript 2d] ethylene present an informative example of how to use group theory to determine the configuration state functions associated with the six states arising from this configuration.
Division of Chemical Education, Inc. and ACS Publications Division of the American Chemical Society. 1155 Sixteenth Street NW, Washington, DC 20036. Tel: 800-227-5558; Tel: 202-872-4600; e-mail: eic@jce.acs.org; Web site: http://pubs.acs.org/jchemeduc
Publication Type: Journal Articles; Reports - Evaluative
Education Level: Higher Education; Postsecondary Education
Audience: N/A
Language: English
Sponsor: N/A
Authoring Institution: N/A
Grant or Contract Numbers: N/A