In the enterprise development process, many companies put on the corporate culture and employee knowledge of psychological capital to stay in their respective functional areas, and can not really establish a humanistic ideas, nor will it recognize employees of psychological capital in the building of enterprise culture in the transmission and amendments to the role of corporate culture has led to the actual out of touch with employees, corporate culture can not achieve the desired results. Based on the corporate culture factors, staff factors affecting the psychological capital, define and analyze the introduction of corporate culture and employee fit the psychological factors of capital as an intermediary variable, and then study its outcome variables to explore the corporate culture and employee fit the relationship between psychological capital, build corporate culture and employee fit model of psychological capital. In this thesis, 10000 employees survey, empirical study found that employees in the corporate culture and fit the psychological capital, intermediate variables and outcome variables was significant positive correlation, based on empirical analysis of comments and suggestions.