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ERIC Number: EJ1062358
Record Type: Journal
Publication Date: 2015-May
Pages: 8
Abstractor: As Provided
Reference Count: 32
ISBN: N/A
ISSN: ISSN-0021-9584
Mechanisms before Reactions: A Mechanistic Approach to the Organic Chemistry Curriculum Based on Patterns of Electron Flow
Flynn, Alison B.; Ogilvie, William W.
Journal of Chemical Education, v92 n5 p803-810 May 2015
A significant redesign of the introductory organic chemistry curriculum at the authors' institution is described. There are two aspects that differ greatly from a typical functional group approach. First, organic reaction mechanisms and the electron-pushing formalism are taught before students have learned a single reaction. The conservation of electrons, atoms, and formal charges, how the use of curved arrows helps describe the mechanism, and how to predict reaction mechanisms are emphasized. Second, the reactions taught in the first two semesters of organic chemistry are arranged by their governing mechanism, rather than by functional group. The reactions are taught in order of increasing difficulty, beginning with acid-base reactions, followed by simple additions to p electrophiles, and ending the first semester with addition to p nucleophiles, including aromatic chemistry. The reactions in the second organic semester begin with elimination reactions, then substitutions, and finally more complex p nucleophile mechanisms (e.g., aldol reaction) and p electrophile reactions (e.g., acetals). Ultimately, the goal is for students to learn and interpret reactions based on their patterns of reactivity, allowing them to analyze, predict, and explain new reactions. In principle, a mechanistic method is more general, easier to understand, and provides a better way to achieve a deep understanding of chemical reactivity. Chemical reactions follow patterns, and these patterns can allow a chemist to predict how a chemical will behave, even if they have never seen a particular reaction before. Visualizing reactivity as a collection of patterns in electron movement is a more powerful and systematic way to approach learning in organic chemistry. It still requires some memorization, but because the course organization is directly linked to reaction patterns, deeper learning in the discipline is possible.
Division of Chemical Education, Inc and ACS Publications Division of the American Chemical Society. 1155 Sixteenth Street NW, Washington, DC 20036. Tel: 800-227-5558; Tel: 202-872-4600; e-mail: eic@jce.acs.org; Web site: http://pubs.acs.org/jchemeduc
Publication Type: Journal Articles; Reports - Descriptive
Education Level: Higher Education; Postsecondary Education
Audience: Teachers
Language: English
Sponsor: N/A
Authoring Institution: N/A
Identifiers - Location: Canada (Ottawa)