ERIC Number: EJ1062274
Record Type: Journal
Publication Date: 2015-Apr
Abstractor: As Provided
Reference Count: 30
Development, Construction, and Operation of a Multisample Volumetric Apparatus for the Study of Gas Adsorption Equilibrium
Ribeiro, Rui P. P. L.; Silva, Ricardo J. S.; Esteves, Isabel A. A. C.; Mota, Jose´ P. B.
Journal of Chemical Education, v92 n4 p757-761 Apr 2015
The construction of a simple volumetric adsorption apparatus is highlighted. The setup is inexpensive and provides a clear demonstration of gas phase adsorption concepts. The topic is suitable for undergraduate chemistry and chemical engineering students. Moreover, this unit can also provide quantitative data that can be used by young researchers to screen the adsorption capacity of different adsorbent materials for various gases. A Labview-based interface was developed to allow the students to perform automated data acquisition and unit control. The laboratorial setup permits the simultaneous measurement of gas adsorption equilibrium on two adsorbent samples, up to 20 bar over a wide temperature range (303-1373 K). The quality of the obtained data was validated by comparison with adsorption isotherms recorded on a high-precision gravimetric apparatus. For this purpose, adsorption equilibria of carbon dioxide (CO[subscript 2]) at 303 and 353 K and nitrogen (N[subscript 2]) at 323 K were recorded on a commercial sample of metal-organic framework MIL-53(Al) as well as on activated carbon. The recorded data were in good agreement with the data obtained by gravimetry, which suggests the validity of the data produced using the new setup.
Descriptors: Science Equipment, Material Development, Science Materials, Scientific Concepts, Undergraduate Students, Chemistry, Engineering Technology, Chemical Engineering, Laboratory Equipment, Hands on Science, Program Descriptions, Scientific Methodology, Teaching Methods, Measurement Equipment
Division of Chemical Education, Inc and ACS Publications Division of the American Chemical Society. 1155 Sixteenth Street NW, Washington, DC 20036. Tel: 800-227-5558; Tel: 202-872-4600; e-mail: firstname.lastname@example.org; Web site: http://pubs.acs.org/jchemeduc
Publication Type: Journal Articles; Reports - Descriptive
Education Level: Higher Education; Postsecondary Education
Authoring Institution: N/A