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ERIC Number: EJ1002730
Record Type: Journal
Publication Date: 2012-Sep
Pages: 3
Abstractor: As Provided
Reference Count: 8
ISBN: N/A
ISSN: ISSN-0021-9584
An Inexpensive Device for Studying Electrochromism
Ibanez, Jorge G.; Puente-Caballero, Rodrigo; Torres-Perez, Jonatan; Bustos, Daniel; Carmona-Orbezo, Aranzazu; Sevilla, Fortunato B., III
Journal of Chemical Education, v89 n9 p1205-1207 Sep 2012
A novel procedure for the preparation of electrochromic WO[subscript 3] films from readily available materials is presented. It is based on the electrochemical preparation of potassium tungstate from tungsten filaments of incandescent light bulbs in a potassium hydroxide solution. Tungstic acid is then produced by proton exchange using a super-absorbing polymer from a baby diaper. Simple air drying of the tungstic acid produces a tungsten(VI) oxide layer. On the surface of a copper foil or coupon or of a conducting glass, an electrochromic bleached (colorless)-to-colored (blue) transition of this oxide layer is easily observed by applying an external potential with a common power source in an electrochemical cell where the Cu (or the conducting glass) electrode is the cathode and a Pb electrode is the anode. This experiment can be performed in 2-3 h and is suitable for an applied inorganic chemistry or electrochemistry lab course. (Contains 2 figures.)
Division of Chemical Education, Inc and ACS Publications Division of the American Chemical Society. 1155 Sixteenth Street NW, Washington, DC 20036. Tel: 800-227-5558; Tel: 202-872-4600; e-mail: eic@jce.acs.org; Web site: http://pubs.acs.org/jchemeduc
Publication Type: Journal Articles; Reports - Descriptive
Education Level: Higher Education
Audience: N/A
Language: English
Sponsor: N/A
Authoring Institution: N/A