ERIC Number: EJ1002730
Record Type: Journal
Publication Date: 2012-Sep
Pages: 3
Abstractor: As Provided
ISBN: N/A
ISSN: ISSN-0021-9584
EISSN: N/A
An Inexpensive Device for Studying Electrochromism
Ibanez, Jorge G.; Puente-Caballero, Rodrigo; Torres-Perez, Jonatan; Bustos, Daniel; Carmona-Orbezo, Aranzazu; Sevilla, Fortunato B., III
Journal of Chemical Education, v89 n9 p1205-1207 Sep 2012
A novel procedure for the preparation of electrochromic WO[subscript 3] films from readily available materials is presented. It is based on the electrochemical preparation of potassium tungstate from tungsten filaments of incandescent light bulbs in a potassium hydroxide solution. Tungstic acid is then produced by proton exchange using a super-absorbing polymer from a baby diaper. Simple air drying of the tungstic acid produces a tungsten(VI) oxide layer. On the surface of a copper foil or coupon or of a conducting glass, an electrochromic bleached (colorless)-to-colored (blue) transition of this oxide layer is easily observed by applying an external potential with a common power source in an electrochemical cell where the Cu (or the conducting glass) electrode is the cathode and a Pb electrode is the anode. This experiment can be performed in 2-3 h and is suitable for an applied inorganic chemistry or electrochemistry lab course. (Contains 2 figures.)
Descriptors: Science Activities, Inorganic Chemistry, Science Instruction, Energy, Scientific Principles, Science Experiments, Science Laboratories, College Science
Division of Chemical Education, Inc and ACS Publications Division of the American Chemical Society. 1155 Sixteenth Street NW, Washington, DC 20036. Tel: 800-227-5558; Tel: 202-872-4600; e-mail: eic@jce.acs.org; Web site: http://pubs.acs.org/jchemeduc
Publication Type: Journal Articles; Reports - Descriptive
Education Level: Higher Education
Audience: N/A
Language: English
Sponsor: N/A
Authoring Institution: N/A
Grant or Contract Numbers: N/A