This study investigated the performance of fit indexes in selecting a covariance structure for longitudinal data. Data were simulated to follow a compound symmetry, first-order autoregressive, first-order moving average, or random-coefficients covariance structure. We examined the ability of the likelihood ratio test (LRT), root mean square error of approximation (RMSEA), comparative fit index (CFI), and Tucker-Lewis Index (TLI) to reject misspecified models with varying degrees of misspecification. With a sample size of 20, RMSEA, CFI, and TLI are high in both Type I and Type II error rates, whereas LRT has a high Type II error rate. With a sample size of 100, these indexes generally have satisfactory performance, but CFI and TLI are affected by a confounding effect of their baseline model. Akaike's Information Criterion (AIC) and Bayesian Information Criterion (BIC) have high success rates in identifying the true model when sample size is 100. A comparison with the mixed model approach indicates that separately modeling the means and covariance structures in structural equation modeling dramatically improves the success rate of AIC and BIC. (Contains 4 tables and 5 figures.)