The present study examined the relation between individual cognitive structure and several key career decision variables. Specifically, in a sample of college students enrolled in a career development class, the usage of the RIASEC (Realistic, Investigative, Artistic, Social, Enterprising, and Conventional) circumplex (adherence) was examined as it varied across individuals and with career certainty, career decision-making self-efficacy, and interest-occupation congruence. Individual adherence to the RIASEC circumplex as a cognitive structure was related to better career decision outcomes. Changes in adherence as a function of taking a career class were found to be associated with changes in career certainty, career decision-making self-efficacy, and interest-occupation congruence. The results support the importance of thinking about careers in a manner similar to the RIASEC circumplex and the potential value of direct instruction of this model. (Contains 3 figures, 2 tables and 2 footnotes.)