The standard curriculum for introductory chemistry does not reflect the needs of students, is enforced by custom and untenured teachers who deviate from it endanger prospects for tenure. Hence, revision of the introductory curriculum should involve research into actual needs and interests of students and should reflect what modern workers conceive…

An experiment is conducted for the oxidation of iron in a gel using consumer chemicals, which is pertinent to the students' understanding of redox chemistry and of the relative oxidation potentials of various metals. The experiment can be carried out with consumer chemicals that might be purchased at a supermarket and commonly found in the home.

An equation derived by Albert Einstein in 1905 that expresses a relationship between mass and energy, formulated as E = mc(super 2) is discussed with reference to the extent mass is conserved. This query can be used to challenge students and develop their language and critical thinking skills.

Albert Einstein's theory of the Brownian motion, Marian von Smoluchowski's heuristic model, and Perrin's experimental results helped to bring the concept of molecules from a state of being a useful hypothesis in chemistry to objects existing in reality. Central to the theory of Brownian motion is the relation between mean particle displacement and…

The main classes of inorganic compounds is presented to students as a two-dimensional chart and one coordinate of the chart corresponds to the acidic equivalent while the other corresponds to the number of bound water molecules. The chart is intended for those students who can assign a compound to a particular class and can be used at different…

An approach to learning chemical facts that starts with the periodic table and depends primarily on recognizing and completing patterns and following a few simple rules is described. This approach exploits the exceptions that arise and uses them as opportunities for further concept development.

Johann Wolfgang Dobereiner, in 1829, made the first significant attempt to reveal a relation between the properties of the chemical elements and their atomic weights. His groupings remain useful for providing reasonable estimates for the properties and the atomic weights of the trans-lawrencium elements.

A rationale for the difference in the periodic trends in the ionization energy of the transition-metal elements versus the main-group elements is presented. The difference is that in the transition-metal elements, the electrons enter an inner-shell electron orbital, while in the main-group elements, the electrons enter an outer-shell electron…

A project involving the synthesis of several naturally occurring copper double salts using simple aqueous conditions is reported. The ions present in the compound are analyzed using colorimetric, gravimetric, and gas-analysis techniques appropriate for the first-year laboratory and from the percent composition, the empirical formula of each…

The electronic properties of Cu(II) complex with proline are considered to demonstrate the Cotton effect in the visible region. A series of experiments in optical rotatory dispersion spectroscopy with free D- and L-proline and their complexes with the Cu(II) ion in aqueous solution is suggested.

The chemical and instrumental methods used in the study of transition-metal complexes provide a complete determination of their structure, bonding, and properties. It unites concepts of analytical, inorganic, and physical chemistry in a way that students might appreciate that these areas of chemistry are not different.

The quantity of information available on Co(III)-pentaammine complexes to the undergraduate students is based on their dissociatively activated substitution processes. The advanced undergraduate set of experiments is presented that fill an important gap in the understanding of the differences taking place in the substitution mechanisms operating…

A discovery-oriented lab experiment is developed that illustrates the chemoselective nature of reductions using sodium borohydride. Products are of sufficient purity to allow analysis by spectroscopy without further purification.

The S[subscript N]2 reaction of 1-bromohexane and 1-bromobutane with potassium acetate is introduced to address the shortage of suitable laboratory experiments in organic laboratory. The experiment offers a review of some common laboratory techniques including the use of infrared spectroscopy to identify functional groups, the use of GC-MS…

An experiment for the organic chemistry laboratory that involves a template-controlled solid-state reaction is described. The experiment utilizes a template to direct the assembly of an olefin in the solid state that undergoes a [2 + 2] photodimerization.