It is common to modify valuable, sophisticated equipment, originally acquired for other purposes, to adapt it for the needs of educational experiments, with great didactic effectiveness. The present project concerns a setup developed from components of a portable system for energy dispersive x-ray fluorescence spectroscopy (EDXRF). Two educational modules have been developed on the basis of this setup. Module 1 comprises a series of x-ray laboratory exercises investigating basic principles, such as the verification of Moseley's law, Compton's law and the Lambert-Beer law. Module 2 concerns the calibration of the XRF with reference materials, aiming to get quantitative measurements of the elemental composition of objects of cultural interest. The application of the calibrated experimental setup is demonstrated with indicative measurements of metal objects and pigments of wall paintings, in order to discuss their spectra, and their qualitative and quantitative analyses. The setup and the applied experiments are designed as an educational package of laboratory exercises on the one hand for students in natural sciences, and on the other for the education of students who will work in the field of cultural heritage, such as conservation science or archaeological science. (Contains 3 tables and 11 figures.)